Measurement of Electrostatic Potentials above Oriented Single Photosynthetic Reaction Centers

Electrostatic interaction between redox cofactors in photosynthetic reaction centers.

Intramolecular electron transfer within proteins is an essential process in bioenergetics. Redox cofactors are embedded in proteins, and this matrix strongly influences their redox potential. Several cofactors are usually found in these complexes, and they are structurally organized in a chain with distances between the electron donor and acceptor short enough to allow rapid electron tunneling....

Photosynthetic reaction centers.

The capture of solar radiation and the conversion of its free energy into chemical energy involves a sequence of reactions that occur within a physical structure called the photosynthetic RC. Following the initial capture of a photon by antenna pigments, the photon is transferred to the RC pigments, where it gives rise to a separation and stabilization of charge across the photosynthetic membra...

Quantum measurement corrections to CIDNP in photosynthetic reaction centers

Chemically induced dynamic nuclear polarization is a signature of spin order appearing in many photosynthetic reaction centers. Such polarization, significantly enhanced above thermal equilibrium, is known to result from the nuclear spin sorting inherent in the radical pair mechanism underlying long-lived charge-separated states in photosynthetic reaction centers. We will show here that the rec...

Reaction centers of photosynthetic bacteria.

Antennas and Reaction Centers of Photosynthetic Bacteria